不用本金就能赚钱的方法

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现在位置不用本金就能赚钱的方法>技术资料不用本金就能赚钱的方法>产品信息>热点应用>Takasago BINAP 配体及钌类催化剂在不对称氢化反应中的应用

Takasago BINAP 配体及钌类催化剂在不对称氢化反应中的应用

百灵威科技有限公司2013年4月15日 14:11 点击:1478

不用本金就能赚钱的方法BINAPYOUYUKONGJIANWEIZUDA、SHUANGNAIHUANDEXIAOXUANZHANGAIGAO,XIANZHILELIANJIELIANGNAIHUANDEHUAXUEJIANZIYOUXUANZHUAN,KEYULIAO、LAOHEBAPEIHEWUCUIHUAJIXIETONGJINXINGDUIYINGXUANZEXINGFANYING。BINAPJINSHUPEIHEWUCUIHUAJIZAIXITING、TONG、YAANDEBUDUICHENGQINGHUA、GUANHUANYIJIC-CJIANXINGCHENGDENGFANYINGZHONGYINGYONGGUANGFAN。BINAPPEITIJIBINAP Ru CymeneCUIHUAJI、BINAP Ru DimerCUIHUAJI、BINAP Ru AcetateCUIHUAJIHEBINAP Ru Diammine CUIHUAJI,CUIHUAHUOXINGGAO(TOFKEDA30,000YISHANG),DUIYINGXUANZEXINGHAO(ee>95%,SHOULVZUIGAOKEDA99%),GONGHUOWENDING,BINGKETIGONGGONGJINJIDABAOZHUANGDINGZHI,KEMANZUKEYANHESHENGCHANDEBUTONGXUQIU。

BINAP 配体

Technical Notes:
1. Ligand (BINAP) employed in the rhodium-catalyzed asymmetric 1,4-addition of arylalanes on trisubstituted enones.
2. Ligand (TolBINAP) used in the copper-catalyzed asymmetric synthesis of cyclopropanes via tandem conjugate addition and intramolecular enolate trapping.
3. Ligand (XylBINAP) used in the asymmetric reduction of ketone via ruthenium-catalyzed transfer hydrogenation.
4. Ligand (H8-BINAP) for palladium-catalyzed enantioselective hydrogenation of substituted indoles.

References:
1. Angew. Chem. Int. Ed., 2010, 49, 7769.
2. J. Am. Chem. Soc., 2010, 132, 14349.
3. J. Am. Chem. Soc., 2011, 133, 10696.
4. J. Am. Chem. Soc., 2010, 132, 8909.

96-6950 Takasago BINAP Ligand Kit

(R)-(+)-2,2’-Bis(diphenylphosphino)-1,1’-binaphthyl, 98%

(R)-(+)-BINAP []

(R)-(+)-2,2’-Bis(di-p-tolylphosphino)-1,1’-binaphthyl, 98%

(R)-(+)-TolBINAP[]

不用本金就能赚钱的方法(R)-(+)-2,2’-Bis[di(3,5-xylyl)phosphino]-1,1’-binaphthyl, 98%

(R)-(+)-XylBINAP[]

不用本金就能赚钱的方法(S)-(-)-2,2’-Bis(diphenylphosphino)-1,1’-binaphthyl, 97%

(S)-(-)-BINAP[]

(S)-(-)-2,2’-Bis(di-p-tolylphosphino)-1,1’-binaphthyl, 98%

不用本金就能赚钱的方法(S)-(-)-TolBINAP[]

(S)-(-)-2,2’-Bis[di(3,5-xylyl)phosphino]-1,1’-binaphthyl, 98% (S)-(-)-XylBINAP

[]

BINAP 钌类催化剂

Technical Note:
1. This catalyst has shown to effect the highly enantioselective hydrogenation of functionalized ketones where the substituents
are dialkylamino, hydoxy, siloxy, carbonyl, ester, amide or thioester.
2. The ruthenium catalyzed hydrogenation of aryl propenoic acid to produce the drug Ibuprofen.
3. Catalyst system that exhibits high catalytic activity and enantioselectivity in the hydrogenation of enamines.

References:
1. Tetrahedron Lett., 2008, 49, 4836.
2. J. Org. Chem., 1996, 61, 5510.
3. Topics Organometal. Chem. 2004, 6, 63
4. J. Org. Chem., 1994, 59, 297.

96-6951 Takasago BINAP Ru Cymene Catalyst Kit

Chloro[(R)-(+)-2,2’-bis(diphenyl-phosphino)-1,1’-binaphthyl](p-cymene) ruthenium(II) chloride

[RuCl(p-cymene)((R)-binap)]Cl[]

不用本金就能赚钱的方法Chloro[(R)-(+)-2,2’-bis(di-p-tolyl-phosphino)-1,1’-binaphthyl](p-cymene) ruthenium(II) chloride

[RuCl(p-cymene) ((R)-tolbinap)]Cl []

Chloro{(R)-(+)-2,2’-Bis[di(3,5-xylyl)phosphino]-1,1’-binaphthyl}(p-cymene)ruthenium(II) chloride

[RuCl(p-cymene)((R)-xylbinap)]Cl[]

Chloro[(S)-(-)-2,2’-bis(diphenyl-phosphino)-1,1’-binaphthyl](p-cymene) ruthenium(II) chloride

不用本金就能赚钱的方法[RuCl(p-cymene) ((S)-binap)]Cl []

不用本金就能赚钱的方法Chloro[(S)-(-)-2,2’-bis(di-p-tolylphosphino)-1,1’-binaphthyl](p-cymene)ruthenium(II) chloride

[RuCl(p-cymene)((S)-tolbinap)]Cl []

不用本金就能赚钱的方法Chloro{(S)-(-)-2,2’-bis[di(3,5-xylyl)phosphino]-1,1’-binaphthyl}(p-cymene)ruthenium(II) chloride

[RuCl(p-cymene) ((S)-xylbinap)]Cl []

96-6952 Takasago BINAP Ru Dimer Catalyst Kit

 Dimethylammonium dichlorotri(μ-chloro)bis[(R)-(+)-2,2’-bis (diphenylphosphino)-1,1’-binaphthyl]diruthenate(II)

[NH2Me2][{RuCl((R)-binap)}2(μ-Cl)3][]

Dimethylammonium dichlorotri(μ-chloro)bis[(R)-(+)-2,2’-bis (di-ptolylphosphino)-1,1’-binaphthyl]diruthenate(II)

[NH2Me2][{RuCl((R)-tolbinap)}2(μ-Cl)3][]

不用本金就能赚钱的方法Dimethylammonium dichlorotri(μ-chloro)bis{(R)-(+)-2,2’-bis [di(3,5-xylyl)phosphino]-1,1’-binaphthyl}diruthenate(II)

[NH2Me2][{RuCl((R)-xylbinap)}2(μ-Cl)3][]

不用本金就能赚钱的方法Dimethylammonium dichlorotri(μ-chloro)bis[(S)-(-)-2,2’-bis (diphenylphosphino)-1,1’-binaphthyl]diruthenate(II)

[NH2Me2][{RuCl((S)-binap)}2(μ-Cl)3][]

不用本金就能赚钱的方法 Dimethylammonium dichlorotri(μ-chloro)bis[(S)-(-)-2,2’-bis (di-ptolylphosphino)-1,1’-binaphthyl]diruthenate(II)

[NH2Me2][{RuCl((S)-tolbinap)}2(μ-Cl)3][]

 Dimethylammonium dichlorotri(μ-chloro)bis{(S)-(-)-2,2’-bis [di(3,5-xylyl)phosphino]-1,1’-binaphthyl}diruthenate(II)

[NH2Me2][{RuCl((S)-xylbinap)}2(μ-Cl)3][]

96-6953 Takasago BINAP Ru Acetate Catalyst Kit

不用本金就能赚钱的方法Diacetate[(R)-(+)-2,2’-bis(di-phenylphosphino)-1,1’-binaphthyl] ruthenium(II)

Ru(OAc)2[(R)-binap][]

Diacetato[(R)-(+)-2,2’-bis(di-p-tolylphosphino)-1,1’-binaphthyl] ruthenium(II)

Ru(OAc)2不用本金就能赚钱的方法[(R)-tolbinap][]

不用本金就能赚钱的方法Diacetato{(R)-(+)-2,2’-bis[di(3,5-xylyl)phosphino]-1,1’-binaphthyl}ruthenium(II)

Ru(OAc)2[(R)-xylbinap] []

Diacetato[(S)-(-)-2,2’-bis(di-phenylphosphino)-1,1’-binaphthyl] ruthenium(II)

Ru(OAc)2[(S)-binap][]

Diacetato[(S)-(-)-2,2’-bis(di-p-tolylphosphino)-1,1’-binaphthyl] ruthenium(II)

Ru(OAc)2[(S)-tolbinap][]

Diacetato{(S)-(-)-2,2’-bis[di(3,5-xylyl)phosphino]-1,1’-binaphthyl}ruthenium(II)

Ru(OAc)2[(S)-xylbinap] []

96-6954 Takasago BINAP Ru Diammine Catalyst Kit

不用本金就能赚钱的方法Dichloro{(R)-(+)-2,2’-bis[di(3,5-xylyl)phosphino]-1,1’-binaphthyl}[(2R)-(-)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II)

RuCl2[(R)-xylbinap][(R)-daipen][]

Dichloro{(R)-(+)-2,2’-bis[di(3,5-xylyl)phosphino]-1,1’-binaphthyl0}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II)

RuCl2[(R)-xylbinap][(R,R)-dpen][]

Chloro{(R)-(+)-2,2’-bis[di(3,5-xylyl)phosphino]-1,1’-binaphthyl}[(2R)-(-)-1-(4-methoxyphenyl)-1’-(4-methoxyphenyl-kC)-3-methyl-1,2-butanediamine]ruthenium(II)

(R)-RUCY™-XylBINAP

Dichloro{(S)-(-)-2,2’-bis[di(3,5-xylyl)phosphino]-1,1’-binaphthyl}[(2S)-(+)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II)

RuCl2[(S)-xylbinap][(S)-daipen][]

不用本金就能赚钱的方法Dichloro{(S)-(-)-2,2’-bis[di(3,5-xylyl)phosphino]-1,1’-binaphthyl}[(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II)

RuCl2不用本金就能赚钱的方法[(S)-xylbinap][(S,S)-dpen][]

Chloro{(S)-(-)-2,2’-bis[di(3,5-xylyl)phosphino]-1,1’-binaphthyl}[(2S)-(+)-1-(4-methoxyphenyl)-1’-(4-methoxyphenyl-kC)-3-methyl-1,2-butanediamine]ruthenium(II)

(S)-RUCY™-XylBINAP []

注:1、以上产品均为Takasago®专利产品;
      2、可提供大包装定制服务。

(来源: 百灵威科技有限公司


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